https://nova.newcastle.edu.au/vital/access/ /manager/Index en-au 5 https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:632 = 20 years significantly depleted carbon concentrations compared with grassy woodlands in the surface 0.20 m at all sites and to a depth of 0.60 m at 3 sites. Depth of sampling (0-0.20 v 0-1.0 m) significantly affected the differences between land uses at most sites regarding estimates of the stock of soil carbon. These results show that differences in soil carbon concentrations and stock size do not remain constant with depth between contrasting land uses. However, comparisons between land uses of the total amount of carbon stored were dominated by the number of trees per ha and the size of the trees in grassy woodlands. The implications of these results for carbon accounting are discussed.]]> Thu 25 Jul 2013 09:10:37 AEST ]]> https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:43454 3). Sorption closely followed pseudo second order kinetics and was best described by the Langmuir model. FTIR analysis suggested that chemisorption was the predominant mechanism of Be sorption. Desorption was very low and best described by the Freundlich model. The low desorption reflected the high K_d (up to 6624 L/kg), and the presence of hysteresis suggested partially irreversible binding of Be with active surfaces of the soil matrix (minerals, SOM, oxyhydroxides of Fe/Al/Mn etc.). Intra-particle diffusion of Be and entrapment in the pores contribute to the irreversible binding. The sorption behaviour of Be helped to explain the relative immobility of Be at the site despite the significant quantities of Be disposed. Soil physicochemical properties were significant for Be sorption, through influencing both the uptake and desorption, and this demonstrates the implications of these measurements for evaluating potential future risks to the environment.]]> Mon 19 Sep 2022 15:12:20 AEST ]]>